Some of the most useful and versatile materials today are the metal-organic frameworks (MOFs). MOFs are a class of materials demonstrating structural versatility, high porosity, fascinating optical and electronic properties, all of which makes them promising candidates for a variety of applications, including gas capture and separation, sensors, and photocatalysis.
Because MOFs are so versatile in both their structural design and usefulness, material scientists are currently testing them in a number of chemical applications. One of these is photocatalysis, a process where a light-sensitive material is excited with light. The absorbed excess energy dislocates electrons from their atomic orbits, leaving behind “electron holes”. The generation of such electron-hole pairs is a crucial process in any light-dependent energy process, and, in this case, it allows the MOF to affect a variety of chemical reactions.
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Image: Simultaneous photocatalytic hydrogen generation and dye degradation using a visible light active metal–organic framework. CREDIT: Alina-Stavroula Kampouri / EPFL