“There’s huge interest in replacing the liquid electrolytes in current batteries with ceramic materials because they’re safer and can provide higher energy density,” said Christos Athanasiou, a postdoctoral researcher in Brown’s School of Engineering and lead author of the research. “So far, research on solid electrolytes has focused on optimizing their chemical properties. With this work, we’re focusing on the mechanical properties, in the hope of making them safer and more practical for widespread use.”

The electrolyte is the barrier between a battery’s cathode and anode through which lithium ions flow during charging or discharging. Liquid electrolytes work pretty well — they’re found in most batteries in use today — but they have some problems. At high currents, tiny filaments of lithium metal can form inside the electrolytes, which cause batteries to short circuit. And since liquid electrolytes are also highly flammable, those shorts can lead to fires.

Read more at: Brown University

Research shows that reduced graphene oxide (rGO) can help prevent the propagation of cracks in ceramic materials used for battery electrolytes. The findings could be a step toward making solid electrolytes that are tough enough for the mass market. (Photo Credit: Sheldon lab / Brown University)